Li vacancy-induced ionic conductivity enhancement in Li4B7O12Cl for all-solid-state Li-ion battery application

Author:

Wang Shaowei1,Gao Zesen1,Sun Futing1,Yang Yan1,Tao Lang1,Wang Yunluo1,Yu Zhiqian2,Wu Jianghua3,Hou Jingshan3ORCID,Liu Zhanqiang4ORCID,Song Hucheng2,Chen Haijie1ORCID

Affiliation:

1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Institute of Functional Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620, People's Republic of China

2. National Laboratory of Solid-State Microstructures, School of Electronics Science and Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing, 210093, People's Republic of China

3. School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai, 201418, China

4. Department of Materials Chemistry, Huzhou University, Huzhou 313000, People's Republic of China

Abstract

Doping Mg into the Li sites of Li4B7O12Cl contributes to the generation of Li vacancies and the enhancement of ionic conductivity.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shanghai Municipality

Fundamental Research Funds for the Central Universities

Huzhou Municipal Science and Technology Bureau

Publisher

Royal Society of Chemistry (RSC)

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