Unveiling the reaction mechanism of novel copperN-alkylated tetra-azacyclophanes with outstanding superoxide dismutase activity

Author:

Martínez-Camarena Álvaro12345ORCID,Sánchez-Murcia Pedro A.678910ORCID,Blasco Salvador678910ORCID,González Leticia678910ORCID,García-España Enrique12345ORCID

Affiliation:

1. ICMol

2. Departamento de Química Inorgánica

3. University of Valencia

4. Paterna

5. Spain

6. Institute of Theoretical Chemistry

7. Faculty of Chemistry

8. University of Vienna

9. A-1090 Vienna

10. Austria

Abstract

One of the first theoretical studies of the reaction mechanism of a small superoxide dismutase mimetic reveals the key role played by the metal bound water molecule and the molecular organisation.

Funder

Ministerio de Economía y Competitividad

Ministerio de Ciencia e Innovación

Austrian Science Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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