Elucidating the intimate mechanism of NAD<sup>+</sup> hydrogenation with phosphonic acid catalysed by Cp*Ir(pyridine-2-sulfonamidate) complexes-Reference-Cited by-同舟云学术

Elucidating the intimate mechanism of NAD⁺ hydrogenation with phosphonic acid catalysed by Cp*Ir(pyridine-2-sulfonamidate) complexes

Published:2023 Issue:23 Volume:13 Page:6743-6750
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Tensi Leonardo¹²^ORCID,Rocchigiani Luca¹^ORCID,Menendez Rodriguez Gabriel¹^ORCID,Mosconi Edoardo³^ORCID,Zuccaccia Cristiano¹,De Angelis Filippo¹,Macchioni Alceo¹^ORCID

Affiliation:

1. Department of Chemistry, Biology and Biotechnology, University of Perugia, Via Elce di sotto 8, 06123, Perugia, Italy

2. Department of Pharmaceutical Sciences, University of Perugia, Via del Liceo 1, 06123, Perugia, Italy

3. Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), Istituto CNR di Scienze e Tecnologie Chimiche “Giulio Natta” (CNR-SCITEC), 06123 Perugia, Italy

Abstract

Cp*Ir(pyridine-2-sulfonamidate) complexes undergo pyridine displacement when catalysing nicotine amide dinucleotide hydrogenation in the presence of phosphonic acid, thus explaining the molecular origin of their improved performance.

Funder

European Commission

Università degli Studi di Perugia

Ministero dell’Istruzione, dell’Università e della Ricerca

Fondazione Cassa di Risparmio di Perugia

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CY/D3CY01048A

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