Metal-substituted tungstosulfates with Keggin structure: synthesis and characterization

Author:

Azuma Shinya12345,Kadoguchi Taiga12345,Eguchi Yohei12345,Hirabaru Hikaru12345,Ota Hiromi678910,Sadakane Masahiro111213145ORCID,Yanagisawa Kazumichi15235,Hasegawa Takuya1617185ORCID,Ueda Tadaharu12345ORCID

Affiliation:

1. Department of Applied Science

2. Faculty of Science

3. Kochi University

4. Kochi

5. Japan

6. Division of Instrumental Analysis

7. Department of Instrumental Analysis and Cryogenics

8. Advanced Science Research Center

9. Okayama University

10. Okayama

11. Department of Applied Chemistry

12. Faculty of Engineering

13. Hiroshima University

14. Hiroshima

15. Hydrothermal Reaction Center

16. Institute of Multidisciplinary Research for Advanced Materials (IMRAM)

17. Tohoku University

18. Sendai

Abstract

Simple synthetic procedures for accessing novel metal-substituted tungstosulfates [SMW11O39]4− (M = Mn2+, Co2+, Ni2+, and Cu2+) with Keggin-type structures were developed.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Hiroshima University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference36 articles.

1. M. T. Pope , Heteropoly and Isopoly Oxometalates , Springer , Berlin , 1983

2. Polyoxometalate Chemistry From Topology via Self-Assembly to Applications , ed. M. T. Pope and A. Müller , Kluwer Academic Publishers , 2001

3. Polyoxometalate Chemistry for Nano-Composite Design , ed. T. Yamase and M. T. Pope , Kluwer Academic/Plenum Publishers , 2002

4. Polyoxometalate Molecular Science , ed. J. J. Borrás-Almenar , E. Coronado , A. Müller and M. T. Pope , Kluwer Academic Publishers , 2003

5. Polyoxometalate Chemistry – Some Recent Trends , ed. F. Secheresse , World Scientific , 2013

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