Synthesis, X-ray characterization and DFT studies of N-benzimidazolyl-pyrimidine–M(ii) complexes (M = Cu, Co and Ni): the prominent role of π-hole and anion

Synthesis, X-ray characterization and DFT studies of N-benzimidazolyl-pyrimidine–M(ii) complexes (M = Cu, Co and Ni): the prominent role of π-hole and anion–π interactions

Published:2015 Issue:31 Volume:17 Page:5987-5997
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Cañellas Santiago¹²³,Bauzá Antonio¹²³,Lancho Aïda¹²³,García-Raso Angel¹²³,Fiol Joan J.¹²³,Molins Elies⁴⁵⁶,Ballester Pablo⁷⁸⁹¹⁰¹¹,Frontera Antonio¹²³^ORCID

Affiliation:

1. Departament de Química

2. Universitat de les Illes Balears

3. 07122 Palma de Mallorca (Baleares), Spain

4. Institut de Ciència de Materials de Barcelona (CSIC)

5. Campus UAB

6. , Spain

7. Institute of Chemical Research of Catalonia (ICIQ)

8. Avgda. Països Catalans 16

9. 43007 Tarragona, Spain and Catalan Institution for Research and Advanced Studies (ICREA)

10. Passeig Lluís Companys, 23

11. Barcelona, Spain

Abstract

Five Cu(ii), Co(ii) and Ni(ii) complexes with 2-(N-benzimidazolyl)-pyrimidine and nitrate co-ligands have been synthesized and characterized by X-ray diffraction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CE/C5CE01009H

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