Kinetic stabilization of a Ni(ii) bis(dithiobenzoate)-type complex achieved using three-dimensional insulation by a [1]rotaxane structure
Author:
Affiliation:
1. Department of Energy and Hydrocarbon Chemistry
2. Graduate School of Engineering
3. Kyoto University
4. Kyoto 615-8510
5. Japan
6. Department of Basic Science
7. Graduate School of Art and Sciences
8. The University of Tokyo
9. Tokyo
Abstract
We describe herein the synthesis of a Ni(ii) bis(dithiobenzoate)-type complex three-dimensionally insulated by a [1]rotaxane structure to reveal the importance of the insulation.
Funder
Japan Society for the Promotion of Science
Mitsubishi Foundation
Nagase Science Technology Foundation
Asahi Glass Foundation
Core Research for Evolutional Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC00351C
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