Spin-crossover modulation via single-crystal to single-crystal photochemical [2 + 2] reaction in Hofmann-type frameworks

Author:

Wang Long-Fei12345,Zhuang Wei-Man12345,Huang Guo-Zhang12345ORCID,Chen Yan-Cong12345ORCID,Qiu Jiang-Zhen12345,Ni Zhao-Ping12345,Tong Ming-Liang12345ORCID

Affiliation:

1. Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education

2. School of ChemistrySun

3. Yat-Sen University

4. Guangzhou

5. 510275 P. R. China

Abstract

Spin-crossover (SCO) system integrated with photochemical [2 + 2] reaction is firstly reported. The dimerization of azastilbene ligands dramatically modulated SCO properties, providing a new strategy for exploiting photo-responsive SCO materials.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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