Spin-crossover modulation via single-crystal to single-crystal photochemical [2 + 2] reaction in Hofmann-type frameworks
Author:
Affiliation:
1. Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education
2. School of ChemistrySun
3. Yat-Sen University
4. Guangzhou
5. 510275 P. R. China
Abstract
Spin-crossover (SCO) system integrated with photochemical [2 + 2] reaction is firstly reported. The dimerization of azastilbene ligands dramatically modulated SCO properties, providing a new strategy for exploiting photo-responsive SCO materials.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC02274K
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