Tropospheric oxidation of methyl hydrotrioxide (CH3OOOH) by hydroxyl radical-Reference-Cited by-同舟云学术

Tropospheric oxidation of methyl hydrotrioxide (CH3OOOH) by hydroxyl radical

Published:2018 Issue:43 Volume:20 Page:27406-27417
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Anglada Josep M.¹²³⁴^ORCID,Solé Albert⁵⁶⁷⁸⁴^ORCID

Affiliation:

1. Departament de Química Biològica

2. (IQAC – CSIC)

3. E-08034 Barcelona

4. Spain

5. Departament de Ciència de Materials i Química Física

6. i Institut de Química Teòrica i Computacional (IQTCUB)

7. Universitat de Barcelona

8. E-08028 Barcelona

Abstract

Hydroxyl radical abstracts the terminal hydrogen atom of CH₃OOOH leading to the formation of CH₃O + O₂ + H₂O (>94% yield), while producing H₂CO + HO₂ + H₂O to a lesser extent.

Funder

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP04486D

Reference60 articles.

1. Three decades of global methane sources and sinks

2. Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry

3. Gas-phase radical chemistry in the troposphere

4. Atmospheric chemistry of VOCs and NOx

5. The Reaction of CH3O2 Radicals with OH Radicals: A Neglected Sink for CH3O2 in the Remote Atmosphere

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