Mechanistic studies on the addition of hydrogen to iridaepoxide complexes with subsequent elimination of water

Author:

Doyle Lauren E.1234,Piers Warren E.1234,Borau-Garcia Javier1234,Sgro Michael J.1234,Spasyuk Denis M.1234

Affiliation:

1. University of Calgary

2. Department of Chemistry

3. Calgary

4. Canada

Abstract

Iridium complexes of the PCsp2P ligand in which the donors are linked by 2,3-benzo[b]thiophene groups engage in the cooperative activation of N2O and the resulting iridaepoxides can be treated with dihydrogen to effect elimination of water and regeneration of the starting iridium complex.

Funder

Natural Sciences and Engineering Research Council of Canada

Canada Research Chairs

Alberta Innovates - Technology Futures

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference43 articles.

1. Topics in Organometallic Chemistry: Organometallic Pincer Chemistry, ed. G. van Koten and D. Milstein, Springer, Heidelberg, 2013

2. Pincer and Pincer-Type Complexes: Applications in Organic Synthesis and Catalysis, ed. Kalman J. Szabo and Ola F. Wendt, Wiley, Weinheim, Germany, 2014

3. Metal-Ligand Cooperation

4. D. Gelman and R.Romm, in Organometallic Pincer Chemistry, ed. G. van Koten and D. Milstein, Springer, Berlin Heidelberg, 2013, vol. 40, ch. 10, pp. 289–317

5. Lewis Acid Activation of Carbodicarbene Catalysts for Rh-Catalyzed Hydroarylation of Dienes

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