Selective reduction of CO2 to a methanol equivalent by B(C6F5)3-activated alkaline earth catalysis
Author:
Affiliation:
1. Department of Chemistry
2. University of Bath
3. Bath, UK
Abstract
Magnesium and calcium hydrido-tris(pentafluorophenyl)borate derivatives catalyse the completely selective reductive hydroboration of CO2 with pinacolborane (HBpin) to provide the methanol equivalent, CH3OBpin.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC00885E
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4. Secondary Coordination Sphere Interactions Facilitate the Insertion Step in an Iridium(III) CO2 Reduction Catalyst
5. Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium Trimethylphosphine Complexes: A Mechanistic Investigation Using High-Pressure NMR Spectroscopy
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