Catalytic enantioselective addition of isocyanoacetate to 3-methyl-4-nitro-5-styrylisoxazoles under phase transfer catalysis conditions-Reference-Cited by-同舟云学术

Catalytic enantioselective addition of isocyanoacetate to 3-methyl-4-nitro-5-styrylisoxazoles under phase transfer catalysis conditions

Published:2015 Issue:43 Volume:13 Page:10609-10612
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Disetti Paolo¹²³⁴⁵,Moccia Maria⁶⁷⁸,Salazar Illera Diana¹²³⁴⁵,Suresh Surisetti¹²³⁴⁵,Adamo Mauro F. A.¹²³⁴⁵

Affiliation:

1. Centre for Synthesis and Chemical Biology (CSCB)

2. Department of Pharmaceutical and Medicinal Chemistry

3. Royal College of Surgeons in Ireland

4. Dublin 2

5. Ireland

6. National Research Council-Institute of Crystallography

7. 70126 Bari

8. Italy

Abstract

The reaction between 3-methyl-4-nitro-5-styrylisoxazoles and ethyl isocyanoacetate proceeded under PTC to give enantioenriched monoadducts in high ee (up to 99%).

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB01880C

Reference64 articles.

1. Isocyanoacetate Derivatives: Synthesis, Reactivity, and Application

2. A Concise Total Synthesis of (±)-Trigonoliimine B

3. α-Metallierte Isocyanide in der Organischen Synthese

4. Synthesis of Cyclic Compounds via Copper-Isonitrile Complexes

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