Reactivity of electrophilic chlorine atoms due to σ-holes: a mechanistic assessment of the chemical reduction of a trichloromethyl group by sulfur nucleophiles-Reference-Cited by-同舟云学术

Reactivity of electrophilic chlorine atoms due to σ-holes: a mechanistic assessment of the chemical reduction of a trichloromethyl group by sulfur nucleophiles

Published:2016 Issue:39 Volume:18 Page:27300-27307
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Caballero-García Guillermo¹²³⁴⁵,Romero-Ortega Moisés⁴⁵⁶³,Barroso-Flores Joaquín¹²³^ORCID

Affiliation:

1. Centro Conjunto de Investigación en Química Sustentable UAEM – UNAM

2. Toluca 50200

3. Mexico

4. Facultad de Química

5. Universidad Autónoma del Estado de México

6. Toluca 50000

Abstract

σ-Holes are shown to promote the electrophilic behavior of chlorine atoms in a trichloromethyl group when bound to an electron-withdrawing moiety.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP04321F

Reference77 articles.

1. σ-hole bonding between like atoms; a fallacy of atomic charges

2. Expansion of the σ-hole concept

3. σ-Holes, π-holes and electrostatically-driven interactions

4. The Halogen Bond

5. Computer Modeling of Halogen Bonds and Other σ-Hole Interactions

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