Cyclic alkyl(amino)iminates (CAAIs) as strong 2σ,4π-electron donor ligands for the stabilisation of boranes and diboranes(4): a synthetic and computational study-Reference-Cited by-同舟云学术

Cyclic alkyl(amino)iminates (CAAIs) as strong 2σ,4π-electron donor ligands for the stabilisation of boranes and diboranes(4): a synthetic and computational study

Published:2023 Issue:12 Volume:52 Page:3869-3876
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Huynh Silvia¹²,Arrowsmith Merle¹²^ORCID,Meier Lukas¹²^ORCID,Dietz Maximilian¹²,Härterich Marcel¹²,Michel Maximilian¹²,Gärtner Annalena¹²,Braunschweig Holger¹²^ORCID

Affiliation:

1. Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

2. Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

Abstract

NMR-spectroscopic, structural and theoretical data of cyclic alkyl(amino)iminate (CAAI)-stabilised boranes synthesised by halosilane elimination from CAAI–SiMe3and haloborane precursors highlight the excellent σ- and π-electron donor ability of CAAIs.

Funder

Julius-Maximilians-Universität Würzburg

Deutsche Forschungsgemeinschaft

Verband der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00298E

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