Investigation of the relationship between the cycle performance and the electronic structure in LiAlxMn2−xO4 (x = 0 and 0.2) using soft X-ray spectroscopy-Reference-Cited by-同舟云学术

Investigation of the relationship between the cycle performance and the electronic structure in LiAlxMn2−xO4 (x = 0 and 0.2) using soft X-ray spectroscopy

Published:2017 Issue:25 Volume:19 Page:16507-16511
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Asakura Daisuke¹²³⁴^ORCID,Nanba Yusuke¹²³⁴,Makinose Yuki¹²³⁴,Matsuda Hirofumi¹²³⁴,Hosono Eiji¹²³⁴

Affiliation:

1. Research Institute for Energy Conservation

2. National Institute of Advanced Industrial Science and Technology

3. Tsukuba

4. Japan

Abstract

We found that the charge-transfer effect from the O 2p to Mn 3d orbitals is closely connected with the cycle performances for LiMn₂O₄ cathode.

Funder

Hattori Hokokai Foundation

Ministry of Economy, Trade and Industry

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP02070H

Reference29 articles.

1. Lithium insertion into manganese spinels

2. The Li1+xMn2O4/C rocking-chair system: a review

3. Manganese oxides for lithium batteries

4. Structural Fatigue in Spinel Electrodes in High Voltage (4 V) Li/Li[sub x]Mn[sub 2]O[sub 4] Cells

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