I2/CHP mediated [1 + 1 + 1 + 1] cyclization of aromatic isocyanides with amines to construct 1,3-diazetidine-2,4-diimine derivatives
Author:
Affiliation:
1. Key Laboratory of Organic Synthesis of Jiangsu Province
2. College of Chemistry
3. Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology
4. Soochow University
5. Suzhou
Abstract
An I2/CHP (cumene hydroperoxide) mediated [1 + 1 + 1 + 1] cyclization of aromatic isocyanides with readily accessible amines via the formation of 4 new C–N bonds has been developed to construct unsymmetric 1,3-diazetidine-2,4-diimine derivatives under mild conditions.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB02255G
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