Calcium-catalysed synthesis of amines through imine hydrosilylation: an experimental and theoretical study-Reference-Cited by-同舟云学术

Calcium-catalysed synthesis of amines through imine hydrosilylation: an experimental and theoretical study

Published:2023 Issue:5 Volume:21 Page:1038-1045
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Boumekla Yougourthen¹,Xia Fengjie¹,Vidal Lucas¹,Totée Cédric¹,Raynaud Christophe¹^ORCID,Ouali Armelle¹^ORCID

Affiliation:

1. ICGM, Univ Montpellier, CNRS, ENSCM, Montpellier, France

Abstract

Ca(NTf2)PF6, generated from commercial precursors, promotes imine hydrosilylation in high yields and is used to prepare a bioactive amine on the gram scale. The mechanistic investigations highlight an unprecedented Si–H activation by the Ca center.

Funder

Centre National de la Recherche Scientifique

Université de Montpellier

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D2OB02243E

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