Hexadecanuclear isobutyrate nanoclusters with a {CoII14CoIII2} core-Reference-Cited by-同舟云学术

Hexadecanuclear isobutyrate nanoclusters with a {CoII14CoIII2} core

Published:2024 Issue:32 Volume:26 Page:4264-4271
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Stati Dumitru¹^ORCID,van Leusen Jan²^ORCID,Kravtsov Victor Ch.¹^ORCID,Krämer Karl³^ORCID,Liu Shi-Xia³^ORCID,Decurtins Silvio³^ORCID,Kögerler Paul²^ORCID,Baca Svetlana G.¹^ORCID

Affiliation:

1. Institute of Applied Physics, Moldova State University, Academiei str. 5, MD2028 Chisinau, Republica Moldova

2. Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany

3. Department of Chemistry, Biochemistry and Pharmaceutical Sciences, W. Inäbnit Laboratory for Molecular Quantum Materials, University of Bern, CH-3012 Bern, Switzerland

Abstract

An effective, simple and convenient approach based on the interaction of tridentate triol-containing ligands and small Co(ii) isobutyrates enables the preparation of Co16-based nanoclusters with a previously unknown mixed-valence {CoIII2CoII14} core.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CE/D4CE00637B

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1. Pt147 Nanoclusters Soft-Landed on WS2 Nanosheets for Catalysis and Energy Harvesting

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4. Molecular cluster route for the facile synthesis of a stable and active Pt nanoparticle catalyst

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