Redox and acidic properties of chalcogenido-substituted mixed-metal polyoxoanions: a DFT study of α-[PW11O39ME]4− (M = Nb, Ta; E = O, S, Se)
Author:
Affiliation:
1. Institute of Functional Material Chemistry
2. Key Laboratory of Polyoxometalate Science of Ministry of Education
3. Faculty of Chemistry
4. Northeast Normal University
5. Changchun 130024
Abstract
Substitution of one O atom by S and Se atoms in POMs enhances the redox and acidic properties.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/QI/C4QI00158C
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