Resonance/off-resonance excitations: implications on the thermal evolution of Eu3+ photoluminescence

Author:

De Arnab1ORCID,Hernández-Rodríguez Miguel A.2ORCID,Carneiro Neto Albano N.2ORCID,Dwij Vivek3,Sathe Vasant3,Carlos Luís D.2ORCID,Ranjan Rajeev1ORCID

Affiliation:

1. Department of Materials Engineering, Indian Institute of Science, Bangalore-560012, India

2. Phantom-g, CICECO – Aveiro Institute of Materials, Physics Department, University of Aveiro, 3810-193, Aveiro, Portugal

3. UGC-DAE Consortium for Scientific Research, Indore, Devi Ahilya University Campus, Indore 452001, India

Abstract

The anomalous behaviour of Eu3+ emission quenching on cooling is explained using experimental/theoretical approaches involving off-resonance excitation. Based on this, a highly sensitive CaTiO3:Eu3+,Er3+ phosphor (Sr = 4.9% K−1 at 83 K) was designed.

Funder

Science and Engineering Research Board

Department of Science and Technology, Ministry of Science and Technology, India

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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