Activation in the rate of oxygen release of Sr0.8Ca0.2FeO3−δ through removal of secondary surface species with thermal treatment in a CO2-free atmosphere

Author:

Luongo Giancarlo1,Bork Alexander H.1ORCID,Abdala Paula M.1ORCID,Wu Yi-Hsuan1ORCID,Kountoupi Evgenia1,Donat Felix1ORCID,Müller Christoph R.1ORCID

Affiliation:

1. Laboratory of Energy Science and Engineering, Department of Mechanical and Process Engineering, ETH Zurich, Leonhardstrasse 21, 8092 Zürich, Switzerland

Abstract

We elucidate the underlying cause of a commonly observed increase in the rate of oxygen release of an oxygen carrier with redox cycling (here specifically for the perovskite Sr0.8Ca0.2FeO3−δ) in chemical looping applications.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Bundesamt für Energie

Swiss Federal Laboratories for Materials Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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