Alkylideneborate zwitterions and C–C coupling by atypical diboration of electron-rich alkynes-Reference-Cited by-同舟云学术

Alkylideneborate zwitterions and C–C coupling by atypical diboration of electron-rich alkynes

Published:2017 Issue:89 Volume:53 Page:12132-12135
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Böhnke Julian¹²³⁴⁵,Braunschweig Holger¹²³⁴⁵^ORCID,Deißenberger Andrea¹²³⁴⁵,Dellermann Theresa¹²³⁴⁵,Dewhurst Rian D.¹²³⁴⁵^ORCID,Jiménez-Halla J. Oscar C.⁶⁷⁸⁹^ORCID,Kachel Stephanie¹²³⁴⁵,Kelch Hauke¹²³⁴⁵,Prieschl Dominic¹²³⁴⁵

Affiliation:

1. Institute for Inorganic Chemistry

2. Julius-Maximilians-Universität Würzburg

3. Am Hubland

4. Germany

5. Institute for Sustainable Chemistry & Catalysis with Boron

6. Departamento de Química

7. Universidad de Guanajuato

8. Noria Alta S/N

9. Mexico

Abstract

The combination of electron-rich diaminoalkynes and ditopic Lewis acids diboranes(4) leads to unusual diboration reactions involving internal Lewis adduct and zwitterion formation and C–C bond formation.

Funder

Julius-Maximilians-Universität Würzburg

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC07409C

Reference36 articles.

1. Metal-Catalyzed Reactions of Organoboronic Acids and Esters

2. Catalytic, Direct Synthesis of Bis(boronate) Compounds

3. Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

4. Metal-Mediated Diboration of Alkynes with [2]Borametalloarenophanes under Stoichiometric, Homogeneous, and Heterogeneous Conditions

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