Stereoelectronic power of oxygen in control of chemical reactivity: the anomeric effect is not alone

Author:

Alabugin Igor V.1ORCID,Kuhn Leah1ORCID,Medvedev Michael G.23ORCID,Krivoshchapov Nikolai V.24ORCID,Vil’ Vera A.2ORCID,Yaremenko Ivan A.2ORCID,Mehaffy Patricia1,Yarie Meysam5ORCID,Terent’ev Alexander O.2ORCID,Zolfigol Mohammad Ali5ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306, USA

2. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation

3. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., 119991 Moscow, Russian Federation

4. Lomonosov Moscow State University, Leninskie Gory 1 (3), Moscow, 119991, Russian Federation

5. Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan 65167, Iran

Abstract

The chameleonic properties of oxygen accounts for the diverse reactivity of O-functionalities and their profound role in organic synthesis.

Funder

Division of Chemistry

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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