Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu3LiRu2O6

Author:

Huang Bin12345,Liu Ziyi6785,Han Yifeng12345,Zhao Shuang12345,Wu Meixia12345,Frank Corey E.9101112ORCID,Greenblatt Martha9101112ORCID,Croft Mark13101112,Quackenbush Nicholas F.1415161712,Liu Sizhan18192012,Tyson Trevor A.18192012,Zhang Lei2122235,Sun Junliang2122235ORCID,Shan Pengfei678524,Dai Jianhong6785,Yu Xiaohui678524,Cheng Jinguang678524ORCID,Li Man-Rong12345ORCID

Affiliation:

1. Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education

2. School of Chemistry

3. Sun Yat-Sen University

4. Guangzhou 510275

5. P. R. China

6. Beijing National Laboratory for Condensed Matter Physics and Institute of Physics

7. Chinese Academy of Sciences

8. Beijing 100190

9. Department of Chemistry and Chemical Biology, Rutgers

10. The State University of New Jersey

11. Piscataway

12. USA

13. Department of Physics and Astronomy, Rutgers

14. Materials Measurement Science Division

15. Material Measurement Laboratory

16. National Institute of Standards and Technology

17. Gaithersburg

18. Department of Physics

19. New Jersey Institute of Technology

20. Newark

21. College of Chemistry and Molecular Engineering

22. Peking University

23. Beijing 100871

24. School of Physical Sciences

Abstract

The two-dimensional honeycomb layered nonmetallic metal Cu3LiRu2O6 exhibits Pauli-like paramagnetic and Mott variable range hopping semiconduction behaviors, which can be significantly suppressed toward a bad-metal state by pressure up to 35 GPa.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Chinese Academy of Sciences

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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