Versatile electrochemical manufacturing of mixed metal sulfide/N-doped rGO composites as bifunctional catalysts for high power rechargeable Zn–air batteries

Author:

Sanchez Jaime S.12,Xia Zhenyuan34ORCID,Mirehbar Keyvan1,Sasidharan Sankar3,Aravindh S. Assa5,Liscio Andrea6ORCID,Sun Jinhua3,Christian Meganne7ORCID,Palma Jesus1ORCID,Palermo Vincenzo34ORCID,Marcilla Rebeca1ORCID

Affiliation:

1. Electrochemical Processes Unit, IMDEA Energy Institute, Avenida Ramón de la Sagra 3, Móstoles, Madrid, 28935, Spain

2. R&D Department, China Three Gorges (Europe) S.A, C. del Príncipe de Vergara, 112, Planta 7, Madrid, 28002, Spain

3. Industrial and Materials Science, Chalmers University of Technology, Hörsalsvägen 7B, Göteborg, 41296, Sweden

4. Consiglio Nazionale delle Ricerche, Istituto per la Sintesi Organica e la Fotoreattività (ISOF), Via Gobetti 101, Bologna, 40129, Italy

5. Sustainable Chemistry & MME, Faculty of Technology, University of Oulu, 90014, Oulu, Finland

6. Consiglio Nazionale delle Ricerche, Istituto per la Microelettronica e Microsistemi (IMM) – Roma Unit, Via del fosso del cavaliere 100, Roma, 00133, Italy

7. Consiglio Nazionale delle Ricerche, Istituto per la Microelettronica e i Microsistemi (IMM), Via Gobetti 101, Bologna, 40129, Italy

Abstract

Electrodeposition was used for direct synthesis of nitrogen-dopged reduced graphene oxide (NrGO) and mixed transition metal sulfides (NCMS). The resulting NCMS/NrGO composite exhibits excellent OER/ORR peroformance as Zn–air battery cathode.

Funder

Ministerio de Ciencia e Innovación

Graphene Flagship

VINNOVA

Stiftelsen Åforsk

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

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