Mechanistic examination of aerobic Pt oxidation: insertion of molecular oxygen into Pt–H bonds through a radical chain mechanism-Reference-Cited by-同舟云学术

Mechanistic examination of aerobic Pt oxidation: insertion of molecular oxygen into Pt–H bonds through a radical chain mechanism

Published:2016 Issue:29 Volume:45 Page:11650-11656
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Keith Jason M.¹²³⁴,Ye Yixin¹²³⁴,Wei Haochuan¹²³⁴,Buck Matthew R.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Colgate University

3. Hamilton

4. USA

Abstract

DFT calculations were performed in an effort to evaluate the mechanism of O₂ insertion into the Pt–H bond of Tp^Me2Pt^IVMe₂H catalyzed by AIBN or light.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00419A

Reference54 articles.

1. Innovation of Hydrocarbon Oxidation with Molecular Oxygen and Related Reactions

2. Recent Advances in Transition Metal Catalyzed Oxidation of Organic Substrates with Molecular Oxygen

3. Palladium-Catalyzed Oxidation of Organic Chemicals with O 2

4. Sustainability in Catalytic Oxidation: An Alternative Approach or a Structural Evolution?

5. Reactions of Late Transition Metal Complexes with Molecular Oxygen

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