A Pd–Sn heterobimetallic catalyst for carbonylative Suzuki, Sonogashira and aminocarbonylation reactions using chloroform as a CO surrogate

Author:

Mohanty Anuradha1,Nayak Mukesh Kumar1,Roy Sujit1ORCID

Affiliation:

1. Organometallics & Catalysis Laboratory, School of Basic Sciences, Indian Institute of Technology Bhubaneswar, Arugul, Jatani, Khurda 752050, Odisha, India

Abstract

A variety of ketones, amides, and aromatic ynones were synthesized in moderate to good yields in the presence of a heterobimetallic PdCl(PPh3)2SnCl3 catalyst by using chloroform as a CO source in a one-pot fashion.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference67 articles.

1. Using carbon dioxide as a building block in organic synthesis

2. Transition-Metal-Catalyzed Utilization of Methanol as a C1 Source in Organic Synthesis

3. Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles

4. J.Falbe , Carbon Monoxide in Organic Synthesis , Springer Verlag , Berlin , 1980

5. G. W.Parshall , Homogeneous Catalysis , Wiley - Interprise Publication , New York , 1980

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