Fluorescent molecular spring that visualizes the extension and contraction motions of a double-stranded helicate bearing terminal pyrene units triggered by release and binding of alkali metal ions

Author:

Taura Daisuke12345ORCID,Shimizu Kaori52364,Yokota Chiaki52364,Ikeda Riho1234,Suzuki Yoshimasa52364,Iida Hiroki52364ORCID,Ousaka Naoki12345ORCID,Yashima Eiji12345ORCID

Affiliation:

1. Department of Molecular and Macromolecular Chemistry

2. Graduate School of Engineering

3. Nagoya University

4. Japan

5. Department of Molecular Design and Engineering

6. Nagoya 464-8603

Abstract

A unique springlike motion of a fluorescent pyrene-terminated double-stranded helicate is visualized by the catch and release of alkali metal ions.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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