Influence of alkyl chain length on the photovoltaic properties of dithienopyran-based hole-transporting materials for perovskite solar cells

Author:

Caicedo-Reina Mauricio1,Pérez-Escribano Manuel2ORCID,Urieta-Mora Javier34ORCID,García-Benito Inés34ORCID,Calbo Joaquín2ORCID,Ortiz Alejandro15ORCID,Insuasty Braulio15ORCID,Molina-Ontoria Agustín4ORCID,Ortí Enrique2ORCID,Martín Nazario34ORCID

Affiliation:

1. Grupo de Investigación de Compuestos Heterocíclicos, Departamento de Química, Facultad de Ciencias Naturales y Exactas, Universidad del Valle, Calle 13 #100-00, 25360, Cali, Colombia

2. Instituto de Ciencia Molecular, Universidad de Valencia, Catedrático José Beltrán 2, 46980, Paterna, Spain

3. IMDEA-Nanociencia, C/Faraday 9, Ciudad Universitaria de Cantoblanco, 28049, Madrid, Spain

4. Departamento de Química Orgánica, Facultad C. C. Químicas, Universidad Complutense de Madrid, Av. Complutense s/n, 28040, Madrid, Spain

5. Center for Research and Innovation in Bioinformatics and Photonics-CIBioFi, Calle 13 #100-00, Edificio E-20, No. 1069, 25360, Cali, Colombia

Abstract

A tailored design of asymmetric hole-transporting materials (HTMs) is reported with the synthesis of a family of new HTMs based on the use of the 5H-dithieno[3,2-b:2′,3′-d]pyran (DTP) moiety endowed with donor p-methoxytriphenylamines.

Funder

Comunidad de Madrid

Ministerio de Ciencia e Innovación

Generalitat Valenciana

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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