Formic acid oxidation on platinum: a simple mechanistic study-Reference-Cited by-同舟云学术

Formic acid oxidation on platinum: a simple mechanistic study

Published:2015 Issue:32 Volume:17 Page:20805-20813
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Schwarz Kathleen A.¹²³⁴,Sundararaman Ravishankar⁵⁶⁴^ORCID,Moffat Thomas P.¹²³⁴,Allison Thomas C.¹²³⁴

Affiliation:

1. National Institute of Standards and Technology

2. Material Measurement Laboratory

3. Gaithersburg

4. USA

5. The Joint Center for Artificial Photosynthesis

6. California

Abstract

Formic acid oxidation on Pt(111) under electrocatalytic conditions occurs when a formate anion approaches the Pt(111) surface in the CH-down orientation, and barrierlessly releases carbon dioxide as the H binds to the surface.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP03045E

Reference63 articles.

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