An investigation of ligand effects on the visible light-induced formation of porphyrin–iron(iv)-oxo intermediates

Author:

Kwong Ka Wai1234,Patel Dharmesh1234,Malone Jonathan1234,Lee Ngo Fung1234,Kash Benjamin1234,Zhang Rui1234ORCID

Affiliation:

1. Department of Chemistry

2. Western Kentucky University

3. Bowling Green

4. USA

Abstract

Depending on the structure of the porphyrin ligands, the visible light photolysis of porphyrin–iron(iii) bromates produced iron(iv)-oxo radical cations or iron(iv)-oxo porphyrins, permitting direct kinetic studies of their oxidation reactions.

Funder

Division of Chemistry

Western Kentucky University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference53 articles.

1. Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations , ed. B. Meunier , Springer-Verlag , Berlin , 2000

2. Dioxygen Activation at Mononuclear Nonheme Iron Active Sites:  Enzymes, Models, and Intermediates

3. S. P. de Visser and W.Nam , in Handbook of Porphyrin Science , ed. K. M. Kadish , K. M. Smith and R. Guilard , World Scientific Publishing , Singapore , 2010 , vol. 10, pp. 85–139

4. Cytochrome P450 Structure, Mechanism, and Biochemistry , ed. P. R. Ortiz de Montellano , Kluwer Academic/Plenum , New York , 3rd edn, 2005

5. Probing Structure-Function Relations in Heme-Containing Oxygenases and Peroxidases

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