Synergy between dynamic covalent boronic ester and boron–nitrogen coordination: strategy for self-healing polyurethane elastomers at room temperature with unprecedented mechanical properties

Author:

Song Kai12345,Ye Wujin12345,Gao Xingchen12345,Fang Huagao12345ORCID,Zhang Yaqiong67845,Zhang Qi910345ORCID,Li Xueliang112345ORCID,Yang Shanzhong12345,Wei Haibing12345ORCID,Ding Yunsheng12345

Affiliation:

1. Department of Polymer Science and Engineering

2. School of Chemistry and Chemical Engineering

3. Hefei University of Technology

4. Hefei

5. China

6. Biomass Molecular Engineering Center

7. School of Forestry and Landscape Architecture

8. Anhui Agricultural University

9. Anhui Province Key Lab of Aerospace Structural Parts Forming Technology and Equipment

10. Institute of Industry & Equipment Technology

11. Anhui Province Key Laboratory of Advanced Catalytic Materials and Reaction Engineering

Abstract

Boron–nitrogen coordination in polyurethane elastomers enhances the dynamics of the boronic ester while introduces inter- and intra-molecular interactions, leading to mechanical robustness and excellent self-healing efficiency simultaneously.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrical and Electronic Engineering,Process Chemistry and Technology,Mechanics of Materials,General Materials Science

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