Single-molecule magnets within polyoxometalate-based frameworks

Author:

Babaei Zarch Malihe1,Mirzaei Masoud1ORCID,Bazargan Maryam1ORCID,Gupta Sandeep K.2ORCID,Meyer Franc2ORCID,Mague Joel T.3ORCID

Affiliation:

1. Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, Mashhad 9177948974, Iran

2. Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany

3. Department of Chemistry, Tulane University, New Orleans, LA, 70118, USA

Abstract

Two polyoxometalate-based frameworks containing holmium and terbium are synthesized. Their single-molecule magnet (SMM) properties are investigated, where weak field-induced SMM behaviour is observed at low temperatures in dynamic magnetic studies.

Funder

Iran Science Elites Federation

Iran National Science Foundation

Alexander von Humboldt-Stiftung

Georg-August-Universität Göttingen

Deutsche Forschungsgemeinschaft

Ferdowsi University of Mashhad

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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