Constructing densely functionalized Hajos–Parrish-type ketones with six contiguous stereogenic centers and two quaternary carbons in a formal [2 + 2 + 2] cycloaddition cascade-Reference-Cited by-同舟云学术

Constructing densely functionalized Hajos–Parrish-type ketones with six contiguous stereogenic centers and two quaternary carbons in a formal [2 + 2 + 2] cycloaddition cascade

Published:2016 Issue:97 Volume:6 Page:95314-95319
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Peng Chieh-Hung¹²³⁴,Hong Bor-Cherng¹²³⁴^ORCID,Raja Arun¹²³⁴,Chang Chun-Wei¹²³⁴,Lee Gene-Hsiang⁵⁶⁷⁴

Affiliation:

1. Department of Chemistry and Biochemistry

2. National Chung Cheng University

3. Chia-Yi 621

4. Republic of China

5. Instrumentation Center

6. National Taiwan University

7. Taipei

Abstract

Efficient construction of Hajos–Parrish-type ketones with six contiguous stereogenic centers in a formal [2 + 2 + 2] cycloaddition cascade. The spontaneous resolution of racemic product without the need for chiral agent has been achieved.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA22430J

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