Functionalization of [Re6Q8(CN)6]4− clusters by methylation of cyanide ligands-Reference-Cited by-同舟云学术

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Functionalization of [Re6Q8(CN)6]4− clusters by methylation of cyanide ligands

Published:2019 Issue:41 Volume:43 Page:16338-16348
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Mikhaylov Maksim A.¹²³,Mironova Alina D.¹²³,Brylev Konstantin A.¹²³⁴²,Sukhikh Taisiya S.¹²³⁴²^ORCID,Eltsov Ilia V.⁴²³^ORCID,Stass Dmitri V.⁴²³⁵²,Gushchin Artem L.¹²³⁴²^ORCID,Kitamura Noboru⁶⁷⁸⁹¹⁰,Sokolov Maxim N.¹²³⁴²^ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry SB RAS

2. 630090 Novosibirsk

3. Russia

4. Novosibirsk State University

5. Voevodsky Institute of Chemical Kinetics and Combustion SB RAS

6. Department of Chemistry

7. Faculty of Science

8. Hokkaido University

9. 060-0810 Sapporo

10. Japan

Abstract

Methylation of anionic cluster complexes [Re₆Q₈(CN)₆]⁴⁻ with ((CH₃)₃O)BF₄ or CF₃SO₃CH₃ afforded homoleptic isonitrile cluster complexes [Re₆Q₈(CH₃NC)₆]²⁺ (Q = S, Se, Te).

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ02971K

Reference77 articles.

1. Unusual Capping Chalcogenide Dependence of the Luminescence Quantum Yield of the Hexarhenium(III) Cyano Complexes [Re6(μ3-E)8(CN)6]4−, E2−= Se2−> S2−> Te2−

2. Hexarhenium(III) Clusters [Re6(μ3-S)8X6]4−(X−= Cl−, Br−, I−) are Luminescent at Room Temperature

3. Spectroscopic and Photophysical Properties of Hexanuclear Rhenium(III) Chalcogenide Clusters

4. Cluster Core Controlled Reactions of Substitution of Terminal Bromide Ligands by Triphenylphosphine in Octahedral Rhenium Chalcobromide Complexes

5. Synthesis, Spectroscopic and Electrochemical Properties, and Electronic Structures of Octahedral Hexatechnetium(III) Clusters [Tc6Q8(CN)6]4− (Q = S, Se)

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4. Molecularly Engineered Room-Temperature Phosphorescence for Biomedical Application: From the Visible toward Second Near-Infrared Window;Chemical Reviews;2023-11-22

5. PEGylation of Terminal Ligands as a Route to Decrease the Toxicity of Radiocontrast Re6-Clusters;International Journal of Molecular Sciences;2023-11-21

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