Organometallic model complexes elucidate the active gallium species in alkane dehydrogenation catalysts based on ligand effects in Ga K-edge XANES-Reference-Cited by-同舟云学术

Organometallic model complexes elucidate the active gallium species in alkane dehydrogenation catalysts based on ligand effects in Ga K-edge XANES

Published:2016 Issue:16 Volume:6 Page:6339-6353
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Getsoian Andrew “Bean”¹²³⁴,Das Ujjal⁵²³⁴,Camacho-Bunquin Jeffrey¹²³⁴,Zhang Guanghui¹²³⁴⁶,Gallagher James R.¹²³⁴,Hu Bo¹²³⁴⁶,Cheah Singfoong⁷⁸⁹⁴,Schaidle Joshua A.⁷⁸⁹⁴,Ruddy Daniel A.⁷⁸⁹⁴,Hensley Jesse E.⁷⁸⁹⁴,Krause Theodore R.¹²³⁴,Curtiss Larry A.⁵²³⁴,Miller Jeffrey T.¹²³⁴¹⁰,Hock Adam S.¹²³⁴⁶

Affiliation:

1. Chemical Sciences & Engineering

2. Argonne National Laboratory

3. Lemont

4. USA

5. Materials Science Division

6. Department of Chemistry

7. National Bioenergy Center

8. National Renewable Energy Laboratory

9. Golden

10. School of Chemical Engineering

Abstract

Ga(iii)-alkyl and alkoxide model compounds demonstrate XANES edge energy shifts similar to those in Ga dehydrogenation catalysts without a change in Ga oxidation state.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CY/C6CY00698A

Reference80 articles.

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3. Propane conversion over zeolite catalysts: Comments on the role of Ga