Phosphine substitution reactions of (η5-cyclopentadienyl)ruthenium bis(triarylphosphine) chloride, CpRu(PAr3)2Cl {PAr3 = PPh3, P(p-CH3C6H4)3, P(p-FC6H4)3, P(p-CH3OC6H4)3, and PPh2(p-CH3C6H4)}: a tale of two mechanisms-Reference-Cited by-同舟云学术

Phosphine substitution reactions of (η5-cyclopentadienyl)ruthenium bis(triarylphosphine) chloride, CpRu(PAr3)2Cl {PAr3 = PPh3, P(p-CH3C6H4)3, P(p-FC6H4)3, P(p-CH3OC6H4)3, and PPh2(p-CH3C6H4)}: a tale of two mechanisms

Published:2014 Issue:40 Volume:43 Page:15221-15227
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Verschoor-Kirss Michael J.¹²³,Hendricks Olivia¹⁴⁵,Renna Lawrence⁶⁷⁸,Hill David⁶⁷⁸,Kirss Rein U.⁶⁷⁸

Affiliation:

1. Department of Chemistry

2. Colby College

3. Waterville, USA

4. Wellesley College

5. Wellesley, USA

6. Department of Chemistry and Chemical Biology

7. Northeastern University

8. Boston, USA

Abstract

Phosphine substitution in CpRu(PAr₃)₂Cl complexes occurs by competing mechanisms and in some cases is accelerated by added chloride.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT02240H

Reference37 articles.

1. A Ru Catalyzed Divergence: Oxidative Cyclization vs Cycloisomerization of Bis-homopropargylic Alcohols

2. Dinuclear Zinc-Catalyzed Asymmetric Desymmetrization of Acyclic 2-Substituted-1,3-Propanediols: A Powerful Entry into Chiral Building Blocks

3. Cyclopentadienyl Ru II Complexes as Highly Efficient Catalysts for the N ‐Methylation of Alkylamines by Methanol

4. Half-Sandwich Ruthenium(II) Complexes as Catalysts for Stereoselective Carbene−Carbene Coupling Reactions

5. Half-Sandwich Ruthenium(II) Catalysts for C−C Coupling Reactions between Alkenes and Diazo Compounds

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1. Phosphine substitution and linkage isomerization in cyclopentadienylruthenium bis(triphenylphosphine)thiocyanide and selenocyanide, CpRu(PPh₃)₂NCS and CpRu(PPh₃)₂SeCN;Dalton Transactions;2023

2. Kinetics and mechanism of halide exchange in reactions of CpRu(PPh₃)₂Cl with alkyl halides: evidence for radical pairs;New Journal of Chemistry;2023

3. Chloro(η ⁵ ‐Cyclopentadienyl)Bis(Triphenylphosphine)Ruthenium(II) [and Related CpRuX(PR ₃ ) ₂ Complexes];Encyclopedia of Reagents for Organic Synthesis;2022-07-18

4. Kinetics of halide exchange in cyclopentadienylruthenium bis(triarylphosphine)halides;Polyhedron;2022-05

5. Kinetics of phosphine substitution in CpRu(PPh3)2X (X = Cl, Br, I, N3, and NCO);RSC Advances;2017