A density functional study of the photocatalytic degradation of polycaprolactone by the decatungstate anion in acetonitrile solution-Reference-Cited by-同舟云学术

A density functional study of the photocatalytic degradation of polycaprolactone by the decatungstate anion in acetonitrile solution

Published:2024 Issue:15 Volume:26 Page:11746-11754
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Minezawa Noriyuki¹^ORCID,Suzuki Kosuke²^ORCID,Okazaki Susumu¹

Affiliation:

1. Department of Applied Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Chiba 277-8589, Japan

2. Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

Abstract

Density functional theory calculations reveal that decatungstate (W10O324−) photocatalyst can degrade polyester in a one-step hydrogen atom abstraction or two-step process (single electron transfer followed by proton transfer).

Funder

Moonshot Research and Development Program

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00362D

Reference64 articles.

1. Recent Advances in Polyoxometalate-Catalyzed Reactions

2. Decatungstate Anion for Photocatalyzed “Window Ledge” Reactions

3. Polyoxometalate Photocatalysis for Liquid-Phase Selective Organic Functional Group Transformations

4. Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C–H Bonds Elaboration

5. Photoredox-Catalyzed C–H Functionalization Reactions

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