In situ environmental TEM observation of two-stage shrinking of Cu2O islands on Cu(100) during methanol reduction-Reference-Cited by-同舟云学术

In situ environmental TEM observation of two-stage shrinking of Cu2O islands on Cu(100) during methanol reduction

Published:2020 Issue:5 Volume:22 Page:2738-2742
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Chi Hao¹²³⁴,Curnan Matthew T.¹²³⁴⁵^ORCID,Li Meng¹²³⁴^ORCID,Andolina Christopher M.¹²³⁴^ORCID,Saidi Wissam A.⁵²³⁴^ORCID,Veser Götz¹²³⁴⁶,Yang Judith C.¹²³⁴⁷

Affiliation:

1. Department of Chemical and Petroleum Engineering

2. University of Pittsburgh

3. Pittsburgh

4. USA

5. Department of Mechanical Engineering and Materials Science

6. Center for Energy

7. Department of Physics and Astronomy

Abstract

A distinct two-stage reduction of Cu₂O islands under methanol is revealed via combined in situ ETEM, statistical analysis, and DFT calculations.

Funder

Division of Materials Research

Division of Chemical, Bioengineering, Environmental, and Transport Systems

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP05831A

Reference32 articles.

1. The Active Site of Methanol Synthesis over Cu/ZnO/Al 2 O 3 Industrial Catalysts

2. Mechanism of Methanol Synthesis on Cu through CO2 and CO Hydrogenation

3. Quantifying the promotion of Cu catalysts by ZnO for methanol synthesis

4. The Mechanism of CO and CO 2 Hydrogenation to Methanol over Cu‐Based Catalysts

5. Modulation of the selectivity in partial oxidation of methanol over CuZnAl catalysts by adding CO 2 and/or H 2 into the reaction feed

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