Between imide, imidyl and nitrene – an imido iron complex in two oxidation states-Reference-Cited by-同舟云学术

Between imide, imidyl and nitrene – an imido iron complex in two oxidation states

Published:2022 Issue:26 Volume:13 Page:7907-7913
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Reith Sascha¹^ORCID,Demeshko Serhiy²,Battistella Beatrice³^ORCID,Reckziegel Alexander¹,Schneider Christian¹^ORCID,Stoy Andreas¹,Lichtenberg Crispin¹^ORCID,Meyer Franc²^ORCID,Munz Dominik⁴⁵^ORCID,Werncke C. Gunnar¹^ORCID

Affiliation:

1. Philipps-University Marburg, Department of Chemistry, Hans-Meerwein-Str. 4, D-35037 Marburg, Germany

2. University of Göttingen, Institute of Inorganic Chemistry, Tammannstr. 4, D-37077 Göttingen, Germany

3. Humboldt-University, Berlin Institute for Chemistry, Brook-Taylor-Str. 2, D-12489 Berlin, Germany

4. Saarland University, Inorganic Chemistry: Coordination Chemistry, Campus C4.1, D-66123 Saarbrücken, Germany

5. Friedrich-Alexander University Erlangen-Nürnberg, Inorganic Chemistry, Egerlandstr. 1, D-91058 Erlangen, Germany

Abstract

A pair of trigonal imido iron complexes ([Fe(NMes)L2]0,−) in two oxidation states is reported. The anionic complex K{crypt.222}[Fe(NMes)L2] is best described as an iron(ii) imide.

Funder

Deutsche Forschungsgemeinschaft

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC01088G

Reference67 articles.

1. Enantioselective Catalytic Aziridinations and Asymmetric Nitrene Insertions into CH Bonds

2. C-H bond amination by iron-imido/nitrene species