Rotational isomerization: spontaneous structural transformation of a thermally activated delayed fluorescence binuclear copper(<scp>i</scp>) complex-Reference-Cited by-同舟云学术

Rotational isomerization: spontaneous structural transformation of a thermally activated delayed fluorescence binuclear copper(i) complex

Published:2023 Issue:29 Volume:52 Page:9893-9898
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Xiao-Wen¹²³,Huang Chun-Hua¹²⁴,Yang Mingxue¹²,Chen Xu-Lin¹²,Lu Can-Zhong¹²³^ORCID

Affiliation:

1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China

2. Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, Fujian 361021, China

3. School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China

4. The Eighth Affiliated Hospital, Sun Yat-sen University, Shenzhen, 518033, China

Abstract

A new binuclear Cu(i) halide complex, Cu2I2(DPPCz)2, demonstrates spontaneous ligand rotation and coordination configuration transformation, resulting in its conversion to an isomer, without the need for any external stimulation.

Funder

Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China

Youth Innovation Foundation of Xiamen

Natural Science Foundation of Fujian Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01258A

Reference36 articles.