Manipulation of charge carrier flow in Bi4NbO8Cl nanoplate photocatalyst with metal loading

Author:

Ogawa Kanta1ORCID,Sakamoto Ryota1ORCID,Zhong Chengchao1ORCID,Suzuki Hajime1ORCID,Kato Kosaku2ORCID,Tomita Osamu1ORCID,Nakashima Kouichi3,Yamakata Akira2ORCID,Tachikawa Takashi4ORCID,Saeki Akinori5ORCID,Kageyama Hiroshi1ORCID,Abe Ryu1ORCID

Affiliation:

1. Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan

2. Graduate School of Engineering, Toyota Technological Institute, 2-12-1 Hisakata, Tempaku, Nagoya 468-8511, Japan

3. Department of Materials Science and Engineering, College of Engineering, Ibaraki University, 4-12-1, Nakanarusawa, Hitachi, Ibaraki 316-8511, Japan

4. Molecular Photoscience Research Center, Kobe University, 1-1 Rokkodai-cho, Kobe 657-8501, Japan

5. Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

Abstract

An efficient spatial separation of photoexcited carriers is demonstrated in a layered-oxyhalide nanoplate by controlling the direction of carrier flows upon Rh cocatalyst loading, which leads to drastic photocatalytic H2 evolution activity.

Funder

Core Research for Evolutional Science and Technology

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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