Measurement of the conformational switching of azobenzenes from the macro- to attomolar scale in self-assembled 2D and 3D nanostructures

Author:

Quintano Vanesa123,Diez-Cabanes Valentin4567,Dell’Elce Simone893,Di Mario Lorenzo1011123,Pelli Cresi Stefano1011123,Paladini Alessandra1011123ORCID,Beljonne David4567ORCID,Liscio Andrea1314123ORCID,Palermo Vincenzo1231516ORCID

Affiliation:

1. Institute of Organic Synthesis and Photoreactivity (ISOF) – (CNR)

2. 40129 Bologna

3. Italy

4. Laboratory for Chemistry of Novel Materials

5. University of Mons

6. B-7000 Mons

7. Belgium

8. Graphene-XT srl

9. 40123 Bologna

10. Division of Ultrafast Processes in Materials (FLASHit)

11. Institute of Structure of Matter (ISM) – CNR

12. 00133 Rome

13. Institute for Microelectronics and Microsystems (IMM)

14. National Research Council of Italy (CNR)

15. Department of Industrial and Materials Science

16. Chalmers University of Technology

Abstract

We compare the cistrans conformational switching of commercial azobenzene molecules in different chemical environments, ranging from isolated molecules in liquid to attomolar-2D and macro-scale 3D self-assembled structures.

Funder

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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