Silver(i), gold(i) and palladium(ii) complexes of a NHC-pincer ligand with an aminotriazine core: a comparison with pyridyl analogues

Author:

Vaughan Jamila1234,Carter Damien J.56234,Rohl Andrew L.76234,Ogden Mark I.1234,Skelton Brian W.8910114,Simpson Peter V.1234,Brown David H.1234

Affiliation:

1. Department of Chemistry

2. Curtin University

3. Perth WA 6845

4. Australia

5. Science & Maths Education Centre

6. Nanochemistry Research Institute & Department of Chemistry

7. Curtin Institute for Computation

8. Centre for Microscopy

9. Characterisation and Analysis

10. The University of Western Australia

11. Crawley

Abstract

The twisted vs. linear conformation of newly synthesised silver and gold complexes of chelating C,N,C diethylaminotriazinyl-bridged bis(NHC) pincer ligands have been rationalised by computational studies.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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