Switchable dielectric phase transition originating from disorder–order transformation and distortion in {[(C4H4N2)Co(H2O)4]SO4·2H2O}n
Author:
Affiliation:
1. Key Laboratory of Energy Materials Chemistry
2. Ministry of Education
3. Key Laboratory of Advanced Functional Materials, Autonomous Region
4. Institute of Applied Chemistry
5. Xinjiang University
Abstract
Disorder–order transition of the SO42− and distortion of the [(C4H4N2)Co(H2O)4]2+ chain induce the phase transition of {[(C4H4N2)Co(H2O)4]SO4·2H2O}n.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CE/C7CE01096F
Reference35 articles.
1. Synthesis, characterization and disorder–order phase transition of inorganic–organic hybrid materials (H2dabco-CH2-Cl)[MIICl4] (M = Co, Zn)
2. Synthesis, crystal structure and disorder–order phase transition of a new diamine templated metal sulfate, (C3H12N2)2[Cu(H2O)4(SO4)2](HSO4)2
3. Dibenzylammonium trichloroacetate: an above-room-temperature order–disorder switchable dielectric material
4. A spiro-type ammonium based switchable dielectric material with two sequential reversible phase transitions above room temperature
5. Predicting and Screening Dielectric Transitions in a Series of Hybrid Organic-Inorganic Double Perovskites via an Extended Tolerance Factor Approach
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