The loss of CO from [Rh12(μ12-Sn)(CO)27]4−: Synthesis, spectroscopic and structural characterization of the electron-deficient, icosahedral [Rh12(μ12-Sn)(CO)25]4− and [Rh12(μ12-Sn)(CO)26]4− tetra-anions-Reference-Cited by-同舟云学术

The loss of CO from [Rh12(μ12-Sn)(CO)27]4−: Synthesis, spectroscopic and structural characterization of the electron-deficient, icosahedral [Rh12(μ12-Sn)(CO)25]4− and [Rh12(μ12-Sn)(CO)26]4− tetra-anions

Published:2009 Issue:12 Volume: Page:2217
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Femoni Cristina,Iapalucci Maria Carmela,Longoni Giuliano,Tiozzo Cristina,Zacchini Stefano,Heaton Brian T.,Iggo Johnathan A.,Zanello Piero,Fedi Serena,Garland Marc V.,Li Chuanzhao

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2009/DT/B818944G

Reference15 articles.

1. Synthesis, chromatographic separation, and stereophysical analysis of the homologous [Ni12-x(PMe)x(CO)24-3x]2- series (x = 2, 3, 4) containing noncentered Ni12-xPx icosahedral cages and the [Ni10(.mu.5-PMe)2(.mu.4-PMe)5(CO)10]2- dianion containing a structurally unprecedented heptacapped pentagonal prismatic metal cage: structural, spectroscopic, and electrochemical consequences due to replacement of Ni(CO)3 fragments with electronically equivalent (isolobal) PMe fragments

2. Synthesis and structural characterization of the [Ni9(AsPh)3(CO)15]2- and [Ni10(AsMe)2(CO)18]2- dianions containing noncentered icosahedral Ni12-xAsx cores (x = 2, 3): electronically equivalent metal cluster analogs of the regular icosahedral [B12H12]2- dianion

3. Reactions of the [Ni6(CO)12]2- dianion with stibine and bismuthine reagents: synthesis and stereophysical characterization of the [Ni10(SbPh)2(CO)18]2- dianion containing a noncentered icosahedral Ni10Sb2 core and Ni2(CO)4(μ2-Ph2SbOSbPh2)2 containing a centrosymmetric eight-membered (NiSbOSb)2 ring

4. New Nickel−Antimony Carbonyl Clusters: Stereochemical Analyses of the [Ni10(SbR)2(CO)18]2- Dianions (R = Me, Et, iPr, tBu, p-FC6H4) Containing Empty 1,12-Ni10Sb2 Icosahedral Cages and of the Unprecedented Stibinido-Bridged 34-Electron Ni2(CO)4(μ2-SbtBu2)2 Dimer1

5. A new family of metal-centred and noncentred icosahedral cages with transition metal and main group VI atoms: synthesis and structural-bonding analysis of the nickel-centred [Ni11Se2(CO)18]2–, nickel-centred [Ni10Te3(CO)15]2–and noncentred [Ni8Te4(CO)12]2–icosahedral dianions

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