Thermal expansion and magnetic properties of benzoquinone-bridged dinuclear rare-earth complexes

Author:

Moilanen Jani O.1234ORCID,Mansikkamäki Akseli1234ORCID,Lahtinen Manu1234ORCID,Guo Fu-Sheng5678ORCID,Kalenius Elina1234ORCID,Layfield Richard A.5678ORCID,Chibotaru Liviu F.9101112

Affiliation:

1. University of Jyväskylä

2. Department of Chemistry

3. Nanoscience Centre

4. Finland

5. The University of Manchester

6. School of Chemistry

7. M13 9PL Manchester

8. UK

9. Theory of Nanomaterials Group

10. and INPAC-Institute of Nanoscale Physics and Chemistry Katholieke Universiteit Leuven

11. 3001 Leuven

12. Belgium

Abstract

The complexes [BQ(MCl2·THF3)2] (M = Y or Dy) possessing pentagonal bipyramidal environment around metal centers undergo significant thermal expansion as revealed by single-crystal X-ray and powder diffraction experiments.

Funder

Luonnontieteiden ja Tekniikan Tutkimuksen Toimikunta

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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