Tetrakis(1,2,5-thiadiazolo)porphyrazines. 9. Synthesis and spectral and theoretical studies of the lithium(i) complex and its unusual behaviour in aprotic solvents in the presence of acids-Reference-Cited by-同舟云学术

Tetrakis(1,2,5-thiadiazolo)porphyrazines. 9. Synthesis and spectral and theoretical studies of the lithium(i) complex and its unusual behaviour in aprotic solvents in the presence of acids

Published:2019 Issue:37 Volume:48 Page:14049-14061
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Stuzhin Pavel A.¹²³^ORCID,Ivanova Svetlana S.¹²³^ORCID,Hamdoush Mahmoud¹²³^ORCID,Kirakosyan Gayane A.⁴⁵⁶³^ORCID,Kiselev Aleksej¹²³,Popov Anton¹²³,Sliznev Valerij¹²³^ORCID,Ercolani Claudio⁷⁸⁹¹⁰^ORCID

Affiliation:

1. Research Institute of Macroheterocycles

2. Ivanovo State University of Chemical Technology

3. Russia

4. Kurnakov Institute of General and Inorganic Chemistry

5. Russian Academy of Sciences

6. Moscow 119991

7. Dipartimento di Chimica

8. Università di Roma “Sapienza”

9. I-00185 Roma

10. Italy

Abstract

The tetra(1,2,5-thiadiazolo)porphyrazine macrocycle coordinates Li⁺ forming an anionic lithate complex, which undergoes acid-catalyzed delithiation in aprotic solvents affording a dianion – a reactive precursor for the complexation reaction.

Funder

Russian Science Foundation

Ministry of Education and Science of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02345C

Reference55 articles.

1. P. A. Stuzhin and C.Ercolani , Porphyrazines with annulated heterocycles , in The Porphyrin Handbook , ed. K. M. Kadish , K. M. Smith and R. Guilard , Elsevier Science , Amsterdam , 2003 , vol. 15 , pp. 263–364 . 10.1016/B978-0-08-092389-5.50011-0

2. Tetrapyrazinoporphyrazines and their metal derivatives. Part I: Synthesis and basic structural information