KNa0.78Eu0.27In3.80B12S12: a novel hexanary thioborate featuring a B12S12 cluster and diverse InSx (x = 4, 5, 6) units-Reference-Cited by-同舟云学术

KNa_0.78Eu_0.27In_3.80B₁₂S₁₂: a novel hexanary thioborate featuring a B₁₂S₁₂ cluster and diverse InS_x (x = 4, 5, 6) units

Published:2022 Issue:11 Volume:9 Page:2462-2469
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Han Shan-Shan¹,Yu Su-Xin¹,Liu Wenlong¹^ORCID,Guo Sheng-Ping¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, P. R. China

Abstract

A novel thioborate KNa0.78Eu0.27In3.80B12S12 features {[In3.80B12S12]2.6−}∞ framework built by B12S12 clusters and InSx (x = 4, 5, 6) units. Its structural chemistry is well described, and compared with known compounds containing B12Q12 cluster.

Funder

National Natural Science Foundation of China

Qinglan Project of Jiangsu Province of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI00520D

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