Hydrogen atom abstraction reactions independent of C–H bond dissociation energies of organic substrates in water: significance of oxidant–substrate adduct formation-Reference-Cited by-同舟云学术

Hydrogen atom abstraction reactions independent of C–H bond dissociation energies of organic substrates in water: significance of oxidant–substrate adduct formation

Published:2014 Issue:4 Volume:5 Page:1429-1436
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Ishizuka Tomoya¹²³⁴,Ohzu Shingo¹²³⁴,Kotani Hiroaki¹²³⁴,Shiota Yoshihito⁵⁶⁷,Yoshizawa Kazunari⁵⁶⁷,Kojima Takahiko¹²³⁴

Affiliation:

1. Department of Chemistry

2. Graduate School of Pure and Applied Sciences

3. University of Tsukuba

4. Tsukuba, Japan

5. Institute for Materials Chemistry and Engineering

6. Kyushu University

7. Nishi-Ku, Japan

Abstract

Adduct formation between Ru(iv)–oxo complexes and substrates with hydrogen bonding affords condensed transition states for substrate oxidations in water.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C3SC53002G

Reference84 articles.

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2. W. A. Nugent and J. M.Mayer , Metal-Ligand Multiple Bonds , Wiley , New York , 1988

3. B. Meunier , Biomimetic Oxidations Catalysed by Transition Metal Complexes , Imperial College Press , London , 1998

4. Electron-transfer properties of high-valent metal-oxo complexes

5. Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer

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