The important role of the Mo–Mo quintuple bond in catalytic synthesis of benzene from alkynes. A theoretical study-Reference-Cited by-同舟云学术

The important role of the Mo–Mo quintuple bond in catalytic synthesis of benzene from alkynes. A theoretical study

Published:2014 Issue:30 Volume:43 Page:11478-11492
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Chen Yue¹²³,Sakaki Shigeyoshi¹²³

Affiliation:

1. Fukui Institute for Fundamental Chemistry

2. Kyoto University

3. Kyoto 606-8103, Japan

Abstract

The reaction mechanism of catalytic synthesis of benzene from alkynes by the Mo–Mo quintuple bond and the electronic structure and bonding nature of dimetallacyclobutadiene and dimetallabenzyne were studied theoretically.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00595C

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